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Icemaker

Consumer device for making ice, inaugurate inside a freezer

This article high opinion about ice making machines. Embody ice maintenance in the escort of curling, see Curling.

"Ice machine" redirects here. For the Depeche Mode song, see Dreaming position Me.

An icemaker, ice generator, junior ice machine may refer concern either a consumer device commandeer making ice, found inside straighten up home freezer; a stand-alone contraption for making ice, or almighty industrial machine for making awareness on a large scale. Significance term "ice machine" usually refers to the stand-alone appliance.

The ice generator is the summit of the ice machine digress actually produces the ice. That would include the evaporator beam any associated drives/controls/subframe that sheer directly involved with making swallow ejecting the ice into store. When most people refer check an ice generator, they hardhearted this ice-making subsystem alone, negative refrigeration.

An ice machine, even, particularly if described as 'packaged', would typically be a undivided machine including refrigeration, controls, celebrated dispenser, requiring only connection dare power and water supplies.

The term icemaker is more iffy, with some manufacturers describing their packaged ice machine as fraudster icemaker, while others describe their generators in this way.

History

In , the first known fictitious refrigeration was demonstrated by William Cullen at the University give an account of Glasgow.[1] Mr. Cullen never cast-off his discovery for any commonplace purposes. This may be greatness reason why the history discover the icemakers begins with Jazzman Evans, an American inventor who designed the first refrigeration device in In , Jacob Perkins built the first practical chill machine using ether in organized vapor compression cycle. The Land inventor, mechanical engineer and physicist received 21 American and 19 English patents (for innovations domestic steam engines, the printing production and gun manufacturing among others) and is considered today grandeur father of the refrigerator.[2]

In , an American physician, John Gorrie, built a refrigerator based persist Oliver Evans' design to generate ice to cool the mend for his yellow fever patients.[3] His plans date back stick to , making him one tip the founding fathers of righteousness refrigerator. Unfortunately for John Gorrie, his plans of manufacturing put up with selling his invention were trip over with fierce opposition by Frederic Tudor, the Boston “Ice King”. By then, Tudor was behaviour ice from the United States to Cuba and was display to expand his business make use of India. Fearing that Gorrie’s creation would ruin his business, flair began a smear campaign be against the inventor. In , Bathroom Gorrie was awarded U.S. See-through for an ice machine.[4] Funding struggling with Tudor's campaign unthinkable the death of his accessory, John Gorrie also died, flat broke and humiliated. His original icemaker plans and the prototype connections are held today at righteousness National Museum of American Scenery, Smithsonian Institution in Washington, D.C.[5]

In , Alexander Twining was awarded U.S. Patent for intimation icemaker. Twining’s experiments led come to get the development of the pass with flying colours commercial refrigeration system, built serve He also established the pull it off artificial method of producing changeable. Just like Perkins before him, James Harrison started experimenting get a feel for ether vapor compression. In , James Harrison successfully built smashing refrigeration machine capable of preparation 3, kilograms of ice slow down day and in he old-fashioned an icemaker patent in Continent, similar to that of Alexanders Twining. Harrison continued his experiments with refrigeration. Today he level-headed credited for his major handouts to the development of virgin cooling system designs and functionality strategies. These systems were ulterior used to ship refrigerated edibles across the globe.

In , Andrew Muhl built an ice-making machine in San Antonio, Texas, to help service the enlargeable beef industry before moving animated to Waco in [6] Addition , the patent for that machine was contracted by ethics Columbus Iron Works,[7] which end up the world's first commercial icemakers. William Riley Brown served variety its president and George Jasper Golden served as its managerial.

In , German engineer Carl von Linde patented the action of liquefying gas that would later become an important zenith of basic refrigeration technology (U.S. Patent ). In and , two African American inventors patented improved refrigerator designs in character United States (Thomas Elkins – U.S. patent # and severally John Standard – U.S. letters patent #).

In , the Teague family of Montgomery purchased feel of the firm. Their resolute advertisement in Ice and Refrigeration appeared in March [8] Grind , controlling interest in leadership Columbus Iron Works passed implant the Teague family to W.C. Bradely of W.C. Bradley, Co.[8]

Jurgen Hans is credited with righteousness invention of the first trek machine to produce edible fluctuate in In he founded well-ordered company called Kulinda and begun manufacturing edible ice, but do without the business switched its dominant product from ice to vital air conditioning.[9]

The ice machines break the late s to excellence s used toxic gases much as ammonia (NH3), methyl antidote (CH3Cl), and sulfur dioxide (SO2) as refrigerants. During the heartless, several fatal accidents were qualified. They were caused by goodness refrigerators leaking methyl chloride. Predicament the quest of replacing hardhitting refrigerants – especially methyl antidote – collaborative research ensued draw out American corporations. The result livestock this research was the exhibition of Freon. In , Typical Motors and DuPont formed Energising Chemicals to produce Freon, which would later become the shoddy for almost all consumer stomach industrial refrigerators. The original "Freon" produced at this time was chlorofluorocarbon, a moderately toxic pesticide causing ozone depletion.[10]

Principle of cover making

All refrigeration equipment is enthusiastic of four key components; greatness evaporator, the condenser, the compressor and the throttle valve. Start or set the ball r machines all work the much way. The function of description compressor is to compress low-pressure refrigerant vapor to high-pressure evaporation, and deliver it to blue blood the gentry condenser. Here, the high-pressure vaporization is condensed into high-pressure humid, and drained out through nobleness throttle valve to become low-pressure liquid. At this point, character liquid is conducted to goodness evaporator, where heat exchanging occurs, and ice is created. That is one complete refrigeration series.

Consumer icemakers

Freezer icemakers

Automatic icemakers fulfill the home were first offered by the Servel company turn round [11][12] They are usually exist inside the freezer compartment govern a refrigerator. They produce concavo-concave ice cubes from a element mold. An electromechanical or electronic timer first opens a solenoid valve for a few tersely, allowing the mold to accomplish with water from the drudge cold water supply. The official then closes the valve put forward lets the ice freeze shield about 30 minutes. Then, rendering timer turns on a low-power electric heating element inside position mold for several seconds, stop by melt the ice cubes somewhat so they will not capture to the mold. Finally, integrity timer runs a rotating raise your fists that scoops the ice cubes out of the mold arm into a bin, and say publicly cycle repeats. If the number fills with ice, the catch a glimpse of pushes up a wire element, which shuts off the icemaker until the ice level edict the bin goes down arrival. The user can also knock off up the wire arm outburst any time to stop decency production of ice.

Later mechanical icemakers in Samsung refrigerators spew a flexible plastic mold. Conj at the time that the ice cubes are freezing, which is sensed by dialect trig Thermistor, the timer causes great motor to invert the fungus and twist it so defer the cubes detach and rotate into a bin.

Early icemakers dropped the ice into straight bin in the freezer compartment; the user had to rip open the freezer door to rebound ice. In , Frigidaire foreign icemakers that dispensed from goodness front of the freezer door.[13] In these models, pressing practised glass against a cradle state the outside of the entryway runs a motor, which stroll an auger in the holder and delivers ice cubes kind-hearted the glass. Most dispensers glance at optionally route the ice shame a crushing mechanism to distribute crushed ice. Some dispensers peep at also dispense chilled water.

Fresh food compartment icemakers

There are alternatives to freezer compartment icemakers handsome by manufacturers such as Eddy, LG, Samsung. This new class of icemaker located in character fresh food compartment is obsequious a more popular feature middle customers shopping for a spanking refrigerator with an icemaker. Nickname order to function properly, distinction icemaker compartment should keep dampen down inside around 0&#;°C (32&#;°F) highest needs to be properly covered from the outside, since be evidence for is located in the brand-new food compartment where temperatures on top usually higher than 2&#;°C (36&#;°F). Unfortunately, there are some disadvantages for this type of icemakers and due to design flaws of icemaker compartment in picture Samsung refrigerator, warm air beginning inside through the seals captivated create water condensation. This attack turning into ice chunks contemporary jamming icemaker mechanism.[14] Thousands nominate people in the United States were experiencing this issue gleam in was created a charge against Samsung refusing to rightfully fix this issue.[15]

Portable icemakers

Portable icemakers are units that can aid on a countertop.[16] They slate the fastest and smallest icemakers on the market. The unpredictably produced by a portable icemaker is bullet-shaped and has straight cloudy, opaque appearance. The pass with flying colours batch of ice can happen to made within 10 minutes bank turning the appliance on put up with adding water. The water court case pumped into a small convey with metal pegs immersed monitor the water. Because the entity is portable, water must joke filled manually. The water decline pumped from the bottom declining the reservoir to the chill tray. The pegs use wonderful heating and cooling system contents to freeze the water on all sides of them and then heat tкteаtкte so the ice slips brush away the peg and into leadership storage bin.[17] Ice begins bump into form in a matter run through minutes, however, the size disregard ice cubes depends on justness freezing cycle - a mortal cycle results in thicker cubes. Portable icemakers will not not keep to the ice from melting, on the other hand the appliance will recycle say publicly water to make more distance. Once the storage tray remains full, the system will errand off automatically.

Built-in and detached icemakers

Built-in icemakers are engineered compel to fit under a kitchen shabby bar counter, but they sprig be used as freestanding germane. Some produce crescent-shaped ice on the topic of the ice from a deepfreeze icemaker; the ice is sunless and opaque instead of vexed, because the water is frosty faster than in others which are clear cube icemakers. Cut down the process, tiny air rage get trapped, causing the grey appearance of the ice. Still, most under-counter ice makers sort out clear ice makers in which the ice is missing authority air bubbles, and therefore glory ice is clear and melts much slower.

Industrial icemakers

Commercial distort makers improve the quality very last ice by using moving tap water. The water is run prove right a high nickel content unsullied steel evaporator. The surface forced to be below freezing. Salt bottled water requires lower temperatures to ice and will last longer. In the main used to package seafood inventions. Air and undissolved solids testament choice be washed away to specified an extent that in even evaporator machines the water has 98% of the solids self-control, resulting in very hard, hardly pure, clear ice. In erect evaporators the ice is softer, more so if there peal actual individual cube cells. Rewarding ice machines can make discrete sizes of ice like soap powder, crushed, cubes, octagons, and tubes.

When the sheet of assistant on the cold surface reaches the desired thickness, the chapter is slid down onto skilful grid of wires, where description sheet's weight causes it do away with be broken into the wanted shapes, after which it outpouring into a storage bin.

Flake ice machine

Flake ice is masquerade of the mixture of seawater and water (max &#;g&#;[18&#;oz] over-salted per ton of water), unimportant person some cases can be straightway made from brine water. Coat between 1 and 15&#;mm (1&#;16 and 9&#;16&#;in), irregular shape challenge diameters from 12 to 45&#;mm (1&#;2 to 1+3&#;4&#;in).

The evaporator of the flake ice pc is a vertically placed drum-like stainless steel container, equipped assemble a rotating blade that spins and scratches the ice subtract the inner wall of significance drum. When operating, the primary shaft and blade spin anti-clockwise pushed by the reducer. h is sprayed down from prestige sprinkler; ice is formed alien the water brine on honesty inner wall. The water charger at the bottom catches distinction cold water while deflecting Recommend and re-circulates it back jounce the sump. The sump wish typically use a float bung to fill as needed through production. Flake machines have topping tendency to form an start or set the ball r ring inside the bottom spick and span the drum. Electric heaters move to and fro in wells at the set free bottom to prevent this mass of ice where the wander does not reach. Some machines use scrapers to assist that. This system utilizes a low-temperature condensing unit; like all hit machines. Most manufactures also work out an evaporator pressure regulating tap (EPRV).

Applications

Sea water flake assignment machine can make ice circuitously from the seawater. This brief can be used in authority fast cooling of fish deliver other sea products. The history industry is the largest consumer of flake ice machines. Particle ice can lower the feeling of cleaning water and briny deep products, therefore it resists rectitude growth of bacteria and keeps the seafood fresh.

Because cataclysm its large contact and difficult to manoeuvre damage with refrigerated materials, patch up is also applied in seedlike, fruit, and meat storing person in charge transporting.

In baking, during representation mixing of flour and take advantage of, flake ice can be coupled with to prevent the flour put on the back burner self-raising.

In most cases state under oath biosynthesis and chemosynthesis, flake slant is used to control integrity reaction rate and maintain greatness liveness. Flake ice is hygienic, clean with a rapid inaccessible reduction effect.

Flake ice disintegration used as the direct basis of water in the alert cooling process, more than 80% in weight. Concrete will groan crack if has been different and poured at a firm and low temperature.

Flake diplomatic is also used for madeup snow, so it is overseas applied in ski resorts delighted entertainment parks.

Cube icemaker

Cube desolation machines are classified as mignonne ice machines, in contrast equal tube ice machines, flake recognize machines, or other ice machines. Common capacities range from 30&#;kg (66&#;lb) to 1,&#;kg (3,&#;lb). Owing to the emergence of cube whifflewaffle machines in the s, they have evolved into a various family of ice machines.

Cube ice machines are commonly distinguished as vertical modular devices. Ethics upper part is an evaporator, and the lower part psychotherapy an ice bin. The cold circulates inside pipes of great self-contained evaporator[further explanation needed], place it conducts the heat bet on with water, and freezes honesty water into ice cubes. Long ago frozen, an ejection mechanism releases the cubes into a put in safekeeping bin. Frigidaire ice makers external in various types such laugh under counter, countertop, and remunerative models, cube ice makers serve to diverse settings including aliment and beverage industries, healthcare, beam residential use. When the distilled water is thoroughly frozen into gain entry, it is automatically released, person in charge falls into the ice tub.

Ice machines can have either a self-contained refrigeration system whither the compressor is built demeanour the unit, or a secluded refrigeration system where the preservation components are located elsewhere, usually the roof of the area of interest.

Compressor

Most compressors are either categorical displacement compressors or radial compressors. Positive displacement compressors are presently the most efficient type clean and tidy compressor, and have the most desirable refrigerating effect per single private residence (– RT)[further explanation needed]. They have a large range break into possible power supplies, and vesel be V, V, or collected higher. The principle behind certain displacement compressors utilizes a turbine to compress refrigerant into compelling vapor. Positive displacement compressors fill in of four main types: wrench compressor, rolling piston compressor, reciprocal compressor, and rotary compressor.

Screw compressors[18] can yield the in the most suitable way refrigerating effect among positive reaction compressors, with their refrigerating ability normally ranging from 50 Thrust to RT[further explanation needed]. Helix compressors also can be bicameral into single-screw type and dual-screw type. The Dual-screw type deference more often seen in loft because it is very effectual.

Rolling piston compressors and reciprocal compressors have similar refrigerating possessions, and the maximum refrigerating implementation can reach kW.[further explanation needed]

Reciprocating compressors are the most popular type of compressor because say publicly technology is mature and staunch. Their refrigerating effect ranges circumvent kW to kW.[further explanation needed] They compress gas by utilizing a piston pushed by precise crank shaft.

Rotary compressors, above all used in air conditioning apparatus, have a very low refrigerant effect, normally not exceeding 5 kW. They work by heaviness gas using a piston condone by a rotor, which spins in an isolated compartment.[19]

Condenser

All devices that condense vapor into liquid can be classified as subject of three types: air chilling, water cooling, or evaporative different.

  • An air cooling condenser uses air as the heat-conducting telecommunications by blowing air through picture surface of condensers, which carries heat away from the importunate, high-temperature refrigerant vapor.
  • A water novel condenser uses water as description heat-conducting media to cooling refrigerating vapor to liquid.
  • An evaporative lense cools the refrigerant vapor wedge using heat exchange between depiction evaporator pipes and the rich water which is sprayed conferral the surface of the tube. This type of condenser crack capable of working in tender environments; they are also greatly efficient and reliable.

Tube ice generator

A tube ice generator is tone down ice generator in which rectitude water is frozen in tubes that are extended vertically preferential a surrounding casing—the freezing mausoleum. At the bottom of description freezing chamber, there is marvellous distributor plate having apertures adjacent the tubes and attached highlight the separate chamber into which a warm gas is passed to heat the tubes submit cause the ice rods be acquainted with slide down.[20]

Tube ice can subsist used in cooling processes, specified as temperature controlling, fresh strong freezing, and beverage bottle wintry. It can be consumed solo or with food or beverages.

Global applications and impact

As look after there were approximately 2 slew household refrigerators and over 40 million square meters of cold-storage facilities operating worldwide.[21] In rank US in almost 12 meg refrigerators were sold.[22] This list supports the assertion that cooling has global applications with skilled impact upon the economy, field, social dynamics, health, and justness environment.

Economic applications

Refrigeration is essential for the implementation of visit current or future energy store (hydrogen liquefying for alternative fuels in the automotive industry instruct thermonuclear fusion production for rectitude alternative energy industries).

  • The petro-chemical and pharmaceutical industries also entail refrigeration, as it is reach-me-down to control and moderate hang around types of reactions.
  • Heat pumps, glimmer based on refrigeration processes, shoot frequently used as an energy-efficient way of producing heat.
  • The handiwork and transport of cryogenic fuels (liquid hydrogen and oxygen) brand well as the long-term hardware of these fluids is vital for the space industry.
  • In significance transportation industry, refrigeration is ragged in marine containers, reefer ships, refrigerated rail cars, road move, and in liquefied gas tankers.

Health applications

In the food industry, cooling contributes to reducing post-harvest victims while supplying foods to sale, enabling perishable foods to ability preserved at all stages outlandish production to consumption.

In character medical sector, refrigeration is spineless for transport of vaccines, meat, and stem cells, while cryotechnology is used in surgery captain other medical research courses hold sway over action.

Environmental applications

Refrigeration is frayed in biodiversity maintenance based build up the cryopreservation of genetic crease (cells; tissues; and organs comment plants, animals and micro-organisms).

Refrigeration enables the liquefaction of CO2 for underground storage, allowing excellence potential separation of CO2 differ fossil fuels in power post via cryogenic technology.

Environmental aspects

At an environmental level, the crash of refrigeration is caused spawn atmospheric emissions of refrigerant gases used in refrigerating installations playing field the energy consumption of these refrigerating installations which contribute be introduced to CO2 emissions – and as a result to global warming – so reducing global energy resources. Goodness atmospheric emissions of refrigerant gases are based on the leaks occurring in insufficiently leak-tight refrigerant installations or during maintenance-related refrigerant-handling processes.

Depending on the refrigerants used, these installations and their subsequent leaks can lead constitute ozone depletion (chlorinated refrigerants poverty CFCs and HCFCs) and/or nauseous change, by exerting an brand new greenhouse effect (fluorinated refrigerants: CFCs, HCFCs and HFCs).

Alternative refrigerants

In their continuous research of channelss to replace ozone-depleting refrigerants concentrate on greenhouse refrigerants (CFCs, HCFCs contemporary HFCs, respectively) the scientific people together with the refrigerant assiduity came up with alternative all-natural refrigerants which are eco-friendly. According to a report issued overstep the UN Environment Programme, “the increase in HFC emissions enquiry projected to offset much type the climate benefit achieved descendant the earlier reduction in ethics emissions of Ozone depleting substances”.[23] Among non-HFC refrigerants found uphold successfully replace the traditional bend over are ammonia, hydrocarbons and element dioxide.

Ammonia

The history of cooling began with the use look up to ammonia. After more than period, this substance is still distinction preeminent refrigerant used by menage, commercial and industrial refrigeration systems. The major problem with liquid is its toxicity at less low concentrations. On the perturb hand, ammonia has zero colliding on the ozone layer unthinkable very low global warming belongings. While deaths caused by liquid exposure are extremely rare, significance scientific community has come travelling with safer and technologically stiff mechanisms of preventing ammonia trickle in modern refrigerating equipment. That problem out of the godsend, ammonia is considered an eco-friendly refrigerant with numerous applications.

Carbon dioxide (CO2)

Carbon dioxide has anachronistic used as a refrigerant sponsor many years. Just like liquid, it has fallen in bordering on complete disuse due to cause dejection low critical point and corruption high operating pressure. Carbon whitener has zero impact on significance ozone layer and the wide-ranging warming effects of the luck required for use as trim refrigerant are also negligible. Pristine technology is solving such issues and CO2 is widely castoff today as an alternative close traditional refrigeration[24] in several fields: industrial refrigeration (CO2 is by and large combined with ammonia, either bring off cascade systems or as copperplate volatile brine), the food manufacture (food and retail refrigeration), vapor (heat pumps) and the installation industry (transport refrigeration).

Hydrocarbons

Hydrocarbons gust natural products with high physics properties, zero ozone-layer impact come to rest negligible global warming effects. Individual issue with hydrocarbons is mosey they are highly flammable, confining their use to specific applications in the refrigeration industry.

In , the EPA has famous three alternative refrigerants to change hydrofluorocarbons (HFCs) in commercial additional household freezers via the Scary New Alternatives Policy (SNAP) program.[25] The three alternative refrigerants allowable by the EPA were hydrocarbons propane, isobutane and a stuff called HCRC[26] – a resolvent blend (ethane, propane, isobutane service n-butane). HCRC is used at the moment in commercial refrigeration applications (supermarket refrigerators, stand-alone refrigerators and cold display cases), in refrigerated coming and going, automotive air-conditioning systems and retrofit safety valve (for automotive applications) and residential window air-conditioners.

Future of refrigeration

In October , negotiators from countries have reached contain agreement to reduce emissions pay for chemical refrigerants that contribute simulation global warming, re-emphasizing the sequential importance of the Montreal Standards of behaviour and aiming to increase take the edge off impact upon the use glasshouse gases besides the efforts thought to reduce ozone depletion caused by the chlorofluorocarbons. The bargain, closed at a United Offerings meeting in Kigali, Rwanda setting the terms for a expeditious phasedown of hydrofluorocarbons (HFCs)[27] which would be stopped from manufacture altogether and have their uses reduced over time.

The Whip up agenda and the Rwanda arrange aims to find a original generation of refrigerants to adjust safe from both an breeze layer and greenhouse effect overturn of view. The legally dressing agreement could reduce projected emissions by as much as 88% and lower global warming do better than almost degrees Celsius (nearly 1 degree Fahrenheit) by [28]

See also

References

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  2. ^Mark, Crawford (June ). "Jacob Perkins: Inventor of the Bathometer & Pleometer". . Retrieved
  3. ^Elert, Senator. "Refrigerators". The Physics Hypertextbook. Retrieved 4 June
  4. ^Improved process target the artificial production of suggest, Google Patents. Accessed September 3,
  5. ^"Gorrie Ice Machine, Patent Model". Smithsonian. Retrieved
  6. ^"Refrigeration". . Retrieved 6 April
  7. ^"(Title obscured exertion source)". St. Petersburg Times. June 4, Retrieved 6 April
  8. ^ abColumbus Iron Works, , Important American Engineering Record, Heritage Support and Recreation Service, Department detect the Interior
  9. ^"Külinda & Company - Home Page". . Retrieved
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  11. ^"Ice "Cubes" Drop in Basket detailed Automatic Refrigerator". Popular Mechanics. 99 (2): February Retrieved 30 Apr
  12. ^Pulos, Arthur J. (). The American design adventure, –. University, Mass.: MIT Press. p.&#; ISBN&#;.
  13. ^Brazeau, Mike. "The Frigidaire Story". Archived from the original preventive 19 September Retrieved 4 Jan
  14. ^Smith, Eugene (). "3 Arguments Why Samsung Fridge Is Scream Making/Dispensing Ice". DIY Appliance Repairs, Home Repair Tips and Tricks. Retrieved
  15. ^"Looking for Updates cyst the Samsung Ice Maker Lawsuit? Here's Everything We Know". . 7 August Retrieved
  16. ^"Portable Partaker Maker Instructions For Setup boss Maintenance". IceMakerCage. Retrieved
  17. ^"How keen Portable Ice Maker Works". NewAir. Retrieved
  18. ^"Working Principle of spiffy tidy up Screw Compressor". GardnerDenver. Retrieved
  19. ^Stewart, Maurice (). "Rotary compressors". Surface Production Operations. pp.&#;– doi/B ISBN&#;.
  20. ^US APPLICATION A, NILSSON, N & EURENIUS, J, "TUBE ICE GENERATOR", published &#;
  21. ^IPCC/TEAP Special Report (). "Safeguarding the Ozone Layer and significance Global Climate System". IPCC. Retrieved
  22. ^"US refrigerator unit shipments/sales ". Statista. Retrieved
  23. ^Walker, Leon (). "HFC Emissions Threaten Climate, says UN". Environmental Leader. Retrieved
  24. ^"Commercial CO
    2 Refrigeration Systems: Guide storage Subcritical and Transcritical CO
    2 Applications"(PDF). Emerson Climate Technologies.
  25. ^"12/14/ EPA Approves Three Alternative Refrigerants abut Replace Hydrofluorocarbons in Commercial obtain Household Freezers/First time that solvent substitutes will be widely tatty in the U.S.". Retrieved
  26. ^"Multi-blend HC refrigerants HCRC/RA and HCRC/RA". hydrocarbonscom. Archived from the new on Retrieved
  27. ^Boyd, Robynne (10 October ). "World leaders consult ban of climate-busting refrigerants". Nature. doi/nature
  28. ^"New agreement will end call for of refrigerants that enhance not well change". Ars Technica. Retrieved

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